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You can get aquarium sealant from petco. Or GE silicone 1 from home depot. If you get the GE make sure it does not have the anti mold stuff in it. You can't use anything anti mold or bacteria just make sure it doesn't say anything on the tube
I would use caulking instead of chalking. Maybe hose clamps or pvc cement depending on what you are trying to seal. Nick is right with his silicone suggestions. Make sure you use aquarium safe of that GE I stuff without the anti mold in it.
Yeah the aquarium sealant is more expensive but I used it. I decided not to cheap out and figured with my luck I should use somethin that is meant for aquariums.